Megumi and Ribbon step on Hime's toes while she attempts to plan a special party to commemorate their 100th day together and in this time learn that they were ignorant of her feelings after she kicks them out.
Megumi has recieved a letter to come to Hime's place. She comes and waits for someone to come to the door and let her inside, and when Ribbon does, she asks Megumi why she came so early, since the party wasn't to begin for two more hours. Megumi has come to help out and before Ribbon can stop her she walks inside. She is quick to yank her backwards and runs to inform Hime, who has just began to make the batter for the cake she was going to make.
Hime comes out of the kitchen and Megumi is quick to assault her with pleads to help out. Hime claims not to need any help and tells Megumi to just go home and come back later, but she refuses and demands to help. It's then Hime spots her clothing and she yells at her for dressing the way she did, since she isn't wearing appropriate clothing.
She holds up the letter again and shows her that because it's a special party, she had to dress up. She then claims the special quality is ruined and has Ribbon bring her the Cure cards. They put something together for her and have Megumi change into a pretty party dress. Megumi instantly falls in love with the dress and compliments Hime for the great job. Hime then tells her to stay there while she's in the kitchen before continuing- only to fall as she reaches for some bowls. They check on her and she tells Megumi to leave the room and that she doesn't want any help making the cake. So, in the hallway she sits with Ribbon and they listen as she noisily prepares. Just to find that both Megumi and Ribbon have snuck in. She is angry with them, but when they claim they can handle the rest she throws them out again.
As she continues, they continue to interrupt and scold her while she works. She tells them that she wants to do it alone and tells them to quit bothering her. They really want to help her but she refuses it and both of them keep budging into her business. It's then the oven has finished with it's temperature and they tell her to hurry up and begin to run around throwing in the rest of the ingredients she needs while she grows angry.
Both of them are happy when they get the cake in the oven and tell her that it will be done in twenty minutes. Then she throws them both out of the house and they head to the lake to wonder why Hime got so angry. Ribbon claims that they did something they shouldn't have due to their excitement and they made Hime feel badly. It's then Yuko approaches and Ribbon is quick to go limp.
Blue comes into the kitchen to see Him and she informs him what they were doing and how she kicked them out. He tells her that they wanted to help her out of love, but she really wanted to do it herself since Megumi helps her so much. He tells her that because it's their special day it would be ruined if they fought, and they hear someone ring the doorbell. Hime goes to check, but to her surprise she finds Seiji there instead, much to her disappointment. This annoys him since she invited him and Blue tells him not to worry since it has nothing to do with him.
Megumi walks with Yuko, having helped her carry her items. She then runs into her shop while she and Ribbon leave. Seiji finds them and once again he claims everyone is treating him like trash that day. He asks Megumi if she fougt with Hime and he asks what she did. He listens to Megumi, who claims she didn't do anything other then help her bake the cake. But suddenly, before she can say anything she feels an overwhelming sadness.
At a wedding, Hosshiwa appears to ruin the sweet event, claiming to hate such things. She then summons a Saiark out of both the groom and bride. A giant cake themed Saiark appears and everyone runs for it while it makes a bunch of desserts and sweets appear.
Blue suddenly feels it and they look through the mirror. Hime leaves, but he tries to tell her that she needs Megumi, however, Hime doesn't listen and transforms into Cure Princess outside. She summons her wings and then flies towards it.
Suddenly Ribbon reveals that the cake was supposed to be a surprise present for Megumi. Which was why she wanted to make it by herself. This makes Megumi feel really bad, while Ribbon fears Hime will chew her out for it. This makes Megumi realize she messed up, and before she can go back to apologize Blue calls her to inform her of the Saiark attack. She worries upon hearing that Princess left on her own and they try to hurry up and get to the wedding area.
Hosshiwa demands more sweet things as Hime arrives, using Princess Dive Bomber on the Saiark. Hosshiwa comments on how weak she looks due to just being by herself, and Hime claims to be strong as a Pretty Cure. Hosshiwa summons her Saiark to attack Hime and she is able to fend it off long enough to perform Princess Ball. Which it easily destroys, so she tries Princess Bullet Machine Gun and this knocks the Saiark down. But it grabs princess and sends her flying into a wall.
Hosshiwa approaches her and continues to taunt her on her poor choice of coming. The Saiark then throws a bunch of strawberry bombs at Hime while she mocks her. To their surprise however, Cure Lovely has shown up and used her shield to protect her. She then uses Lovely Punching Punch on the Saiark, which sends it flying, as well as Hosshiwa.
Princess claims she could have defeated the Saiark by herself, and Lovely apologizes for ruining the surprise. She admits that she didn't realize her feelings and intent with this, while Princess claims she got too caught up in it herself. The two share a laugh and Ribbon reminds them that they need to take care of the Saiark.
Lovely uses Lovely Rising Sword to advert a huge beam of energy from the Saiark. Princess is glad, but she feels badly that she always needs to be bailed out by her. Lovely claims that it isn't true though because Princess helps her in ways she didn't understand before and together they are able to rid the Saiark of its attack and a big, warm light appears. Ribbon tells them to spread the happiness and together the girls perform Twin Miracle Power Shoot.
Everything returns to normal and Hosshiwa takes off after telling them not to get cocky. The girls share happy words with each other and Ribbon gains some new cards and puts them into the book.
Later in the evening everyone sits together. Ribbon announces that it will be a dinner party instead of a tea party and Hime comes out to reveal her special cake they collaborated on. Ribbon is stunned to see that the cake resembles the Saiark a bit, but Megumi is just happy to see it. She asks what the special event is and Hime reveals that they have become friends one hundred days ago. Hime admits that she had no idea, and Hime claims that it doesn't matter because it's a special day for them both. They both cut into the cake while Seiji teasingly asks the if its a wedding ceremony.
- The following attacks are used for the first time:
- Twin Miracle Power Shoot
- Lovely Punching Punch
- Lovely Rising Sword
- Princess Dive Bomber
- Hosshiwa is seen summoning a Saiark for the first time.
- The opening features more scenes for the New Stage 3 Movie.
- Cure Aqua does the 10th Anniversary Message for this episode.
- Hime says that she and Megumi have been friends for 100 days. Which would mean 100 days have passed since episode 1.
- PreCards debuted: Girly PreCard
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